Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Stress corrosion cracking scc stress corrosion cracking is to bear the stress of the alloy in the corrosive environment because of strong expansion of the alternate failure pattern of a generic term. This type of corrosion occurs quickly affecting the metal deeply and damaging it. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. During such operations, intergranular m 23 c 6 carbides develop and consequently chromium depleted zones form. Nondestructive threedimensional mapping of grain shape, crystallographic orientation, and grain boundary geometry by diffraction contrast tomography dct provides opportunities for the study of the interaction between intergranular stress corrosion cracking and microstructure. The cracked tube section exhibited an equiaxed microstructure without any evidence of sensitization or other material deficiencies. Instances of tgscc have been associated with dilute solutions with ph values in the region of 6. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. Observations of intergranular stress corrosion cracking in. The dependence of failure on composition and stress in copper alloys and in stainless steels is.
Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Stress corrosion of austenitic steels is usually transgranular. Note the competing mechanisms of propagation intergranular corrosion vs. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. The potential is typical of those attained by the material under thin, chloridebearing condensate films exposed to air. Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1.
These observations show that nonsensitised boundaries are resistant to stress corrosion cracking, and the crack propagates. The exact degree to which any of these alloys is resistant to any form of corrosion or stress corrosion depends upon its composition, microstructure, and the exact nature of the solution and solution temperature to which it is exposed. Specialized corrosion doehdbk1015193 corrosion ch02 rev. Chloride stress corrosion cracking in austenitic stainless steel is. Steel preheater tube metallurgical technologies, inc. It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries. Generally at lower temperature grain boundaries have more strength than the grains i. Wolski, in nuclear corrosion science and engineering, 2012. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i.
Intergranular stress corrosion cracking an overview. Woollin p, postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels, proc conf stainless steel world 2005, kci publishing, paper no. Intergranular attack is caused by the formation of chromium carbides fe,cr23c6 at grain boundaries, reducing the chromium content and the stability of the passive layer on stainless steels. Stress corrosion cracking international institute of. Mild steels steels with low carbon and low alloy content and stainless steels will. Inter granular corrosion can be detected by ultrasonic and eddy current methods. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Us4162930a austenitic stainless steel having excellent. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking. Ways of propagation of scc scc can proceed in either of two ways. Transgranular, granulated, and intergranular stress corrosion cracking in aisi 304 ss h. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system.
Stress corrosion cracking of an austenitic stainless steel. Stress corrosion cracking can proceed in one of two ways. Transgranular corrosion is a type of localized corrosion which occurs along cracks or faults across the crystals in metals and alloys. Intergranular stress corrosion cracking igscc and transgranular stress corrosion cracking tgscc were found in sensitized 304 stainless steel and only tgscc was found at solution annealed 304 and. The 316ti stainless steel tube cracked by transgranular stress corrosion cracking due to the presence of sulfur and chlorine in a moist environment at elevated temperatures. At low values of stress, failure occurred by brittle intergranular cracking, and at high values of stress, failure occurred by brittle transgranular cracking. A stress corrosion crack was grown through a volume of sensitized austenitic stainless steel mapped with dct. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Transgranular, intergranular, and granulated stress corrosion cracks were observed. Transgranular stress corrosion cracking an overview. The photos above show the microstructure of a type 304 stainless steel. Chloride stress corrosion cracking in austenitic stainless. Intergranular stress corrosion cracking igscc has appeared in heat affected zones of 304 stainless steel as a result of welding operations.
Lippold j and alexandrov b, phase transformations during welding and postweld heat treatment of a 12cr6. In our previous research, the transgranular stress corrosion cracking behavior of 304 stainless steel in 0. This type of corrosion was previously a potential risk for stainless steel because of its high carbon content. Characterization of intergranular stress corrosion cracking of 304. Intergranular stress corrosion cracking resistance of. When fracture occurs through grain boundaries it is called as intergranular fracture and when occurs through grains is called transgranular fracture. No oxide filled, wedgeshaped crack morphology is present, which would. However, with modern steel making methods, it has become possible. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. All licensees of operating boiling water reactors bwrs and holders of construction permits for bwrs subject. Solomon 1 general electric corporate research and development center, p.
Stress corrosion cracking stress corrosion cracking is a failure mode caused by a combination of a susceptible material, stresses and an aggressive environment, figure 1. Intergranular corrosion facts and how to reduce the risk. It lances fine coals contain corrosive elements like. Pdf intergranular cracking of aisi 316ng stainless steel. Sensitizationinduced intergranular stress corrosion cracking igscc of austenitic stainless steels has been extensively studied and is qualitatively well understood. The intergranular penetrations are attributed to general corrosive attack rather than stress corrosion cracking scc. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Gooch introduction although austenitic stainless steels. Intergranular and transgranular stress corrosion cracking. There are two modes of stress corrosion cracking in austenitic stainless steels, namely intergranular and transgranular stress corrosion cracking, i. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
Intergranular attack in welded stresscorrosion resistant. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. I have observed transgranular stress corrosion cracking in a coal injection lance pipe made of 309s grade of austenitic stainless steel. Scc in a 316 stainless steel chemical processing piping system. Nrc position on intergranular stress corrosion cracking igscc in bwr austenitic stainless steel piping generic letter 8801, supplement 1 february 4, 1992 to. Highpurity copper is immune to stress corrosion cracking in most. It lances fine coals contain corrosive elements like chlorides and sulphur at within the blast furnace. Is the transgranular stress corrosion cracking is because of chlorides present in the coal. Transgranular, granulated, and intergranular stress. This reduces the corrosion resistance of the chromium. There is provided a chromiumnickel austenitic stainless steel having improved resistance to intergranular stress corrosion cracking. Transgranular stress corrosion cracking tgscc is the same as igscc, but. Intergranular stress corrosion cracking of austenitic.
It follows the pattern of grains in the individual lattices of the material. This paper discuses the stress corrosion cracking observed when slow strain rate tests were run on aisi 304 stainless steel specimens in oxygenated 288 c water. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The cracking was determined to be classic branched transgranular stress corrosion cracking scc which is common in stainless steel. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Effect of prior cold work on intergranular and transgranular corrosion in type 304 stainless steels. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. Tscc transgranular stress corrosion cracking acronymattic. Transgranular stress corrosion cracking of 304l stainless. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion resistance. The results indicate that the electrochemical contribution to the scc of cu30au in 0.
Duplex stainless steels possess superior resistance to both transgranular and intergranular stress corrosion cracking. This is, of course, a very complex question for a forum like this. Intergranular stress corrosion cracking of welded steel twi. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. With high enough stress level the intergranular scc mechanism can change to transgranular scc cracking at the pearlite nodules. Cracking of stainless steel nozzle sleeve metallurgical. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. The stresses required to initiate and propagate cracking are often low and many failures occur due to residual stresses rather than applied stress. Stress corrosion cracking in the necessary condition is to have tensile strength. Sensitization, intergranular attack, stress corrosion. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Intergranular stress corrosion cracking in inconel heat exchanger tube with the.
Stress corrosion cracking scc stainless steel tubing. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and in many organic liquids containing traces of water. Influence of chromium depletion on intergranular stress. Stress corrosion cracking of brittle fracture surface, but it may also occur in high toughness materials. Why is chloride stress corrosion cracking transgranular. The steel has low carbon and phosphorus content or carbon and phosphorus in solid solution fixed by niobium addition. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Transgranular stress corrosion cracking of highpressure. In this chapter, the conditions for the occurrence of scc are first introduced. Intergranular corrosion is a localized form of attack occurring at the grain boundaries of a metallic materials with nominal or no effect on the grains. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
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